Gemology — Chemical Composition

The Chemistry of Gemstones

From individual atoms to the ionic and covalent bonds that build diamond, corundum, and quartz — explore the chemical building blocks of every gemstone.

Developed by Akila Amarathunga · Gèmelia & Co.

Atoms, Elements, Molecules & Compounds

All matter — every gemstone, every mineral — is composed of atoms. An atom is the smallest unit of a chemical element that retains the properties of that element. Each atom has a nucleus (protons + neutrons) orbited by electrons.

Key concept: A chemical element is a substance made of only one type of atom. A molecule forms when atoms bond together. When different elements combine chemically, the result is a compound — with properties entirely different from its component elements.

Select an atom to explore its structure in 3D. Drag to rotate.

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Of the 90 naturally occurring elements, just eight make up the bulk of the Earth's crust — and therefore the bulk of our gemstones:

Element Symbol Atomic No. Valency Role in Gems
Oxygen O 8 2 Present in nearly all gem minerals (oxides, silicates)
Silicon Si 14 4 Backbone of silicates — quartz, beryl, garnet, tourmaline
Aluminium Al 13 3 Corundum (ruby/sapphire), beryl, feldspar, spinel
Iron Fe 26 2, 3 Colour agent in peridot, almandine garnet, tourmaline
Calcium Ca 20 2 Feldspar (plagioclase), apatite, calcite
Sodium Na 11 1 Feldspar (albite), jadeite
Potassium K 19 1 Orthoclase feldspar (moonstone)
Magnesium Mg 12 2 Peridot, pyrope garnet, spinel

Valency

Electron orbits surround the nucleus in concentric shells, each an energy level. The outermost shell is the valence shell. Elements form compounds by gaining, losing, or sharing electrons to achieve a stable configuration of 2 or 8 electrons in their outer shell.

Valency = the number of electrons an atom gains, donates, or shares. Oxygen (valency 2) needs 2 more electrons. Aluminium (valency 3) donates 3. Silicon (valency 4) shares 4 — making it the backbone of silicate minerals.

Example — Corundum (Al₂O₃): Aluminium has 3 outer electrons, oxygen has 6 and needs 2 more. Two aluminium atoms (2 × 3 = 6 electrons) combine with three oxygen atoms (3 × 2 = 6 needed) → Al₂O₃ — ruby and sapphire.

Variable valency: Some elements like iron have more than one valency. Fe²⁺ (ferrous) forms different compounds than Fe³⁺ (ferric) — this is why heat treatment can change a gemstone's colour by converting Fe²⁺ ↔ Fe³⁺.

Noble gases (helium, neon, argon) already have stable outer shells (2 or 8 electrons) — they have zero valency and are virtually inert.

Bonding

The chemical joining of elements into a compound is called bonding. Two types are critical in gemology: ionic and covalent.

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Important: Minerals seldom contain bonds that are purely ionic or covalent. Most have a transition between both types. The Si–O bond in silicates, for example, is approximately 50% ionic and 50% covalent.

Van der Waals' bonds are very weak bonds. In graphite, three of carbon's four bonds are strong covalent bonds forming sheets, but the fourth is a weak van der Waals' bond — explaining why graphite is soft and slippery, while diamond (all covalent) is the hardest substance known.

Metallic bonding occurs in metals where valence electrons roam freely between positive ions. This makes metals excellent conductors of electricity and heat. Diamond is unique: an electrical insulator yet conducts heat better than most metals.

Bonding & Valency in Gemstones

See how atoms combine using their valencies to form real gemstone compounds. Each 3D model shows the atoms, electron transfer or sharing, and the resulting bond type.

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Gemstone Chemistry by Group

Gemstones can be classified into four chemical groups based on their composition. Each group has characteristic properties related to hardness and durability.

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